Transition Metal Carbonyl Cluster Chemistry

This book provides a comprehensive overview of transition metal carbonyl clusters, exploring their chemistry, synthesis, and applications in catalysis and organic synthesis.

Transition metal carbonyl clusters (TMCCs) have garnered significant attention in the field of chemical research, primarily due to their intriguing structures and remarkable potential for industrial applications. This book, Transition Metal Carbonyl Cluster Chemistry, serves as an introduction to the fundamental aspects of these clusters, covering their bonding, structure, and spectroscopic properties. The initial chapters lay the groundwork by discussing the characterization techniques that are essential for understanding these complex entities.

As the narrative progresses, Transition Metal Carbonyl Cluster Chemistry delves into the synthesis and reactivity of TMCCs. The text emphasizes the unique reaction mechanisms that differentiate clusters from mononuclear metal complexes, highlighting the importance of multiple-bonding sites and heterosite reactivity. Readers will find practical examples and models that correlate cluster structure with electron count, providing a solid framework for understanding the intricate relationships between bonding and molecular structure.

The latter sections of the book focus on the applications of TMCCs in organic synthesis and catalysis. It discusses their role as homogeneous catalysts and explores innovative methods involving solid and biphasic liquid-liquid supported clusters in heterogeneous catalysis. This comprehensive resource is not only beneficial for those embarking on research or postgraduate studies in metal carbonyl clusters and advanced organometallic chemistry, but it also serves as an essential addition to academic libraries and private collections.